Deep-Sea DuraFET: A Pressure Tolerant pH Sensor Designed for Global Sensor Networks

TitleDeep-Sea DuraFET: A Pressure Tolerant pH Sensor Designed for Global Sensor Networks
Publication TypeJournal Article
Year of Publication2016
AuthorsJohnson K.S, Jannasch H.W, Coletti L.J, Elrod V.A, Martz T.R, Takeshita Y, Carlson R.J, Connery J.G
JournalAnalytical Chemistry
Volume88
Pagination3249-3256
Date Published2016/03
Type of ArticleArticle
ISBN Number0003-2700
Accession NumberWOS:000372391500038
Keywordsconcentration scale; inorganic carbon; ocean acidification; seawater ph; water
Abstract

Increasing atmospheric carbon dioxide is driving a long-term decrease in ocean pH which is superimposed on daily to seasonal variability. These changes impact ecosystem processes, and they serve as a record of ecosystem metabolism. However, the temporal variability in pH is observed at only a few locations in the ocean because a ship is required to support pH observations of sufficient precision and accuracy. This paper describes a pressure tolerant Ion Sensitive Field Effect Transistor pH sensor that is based on the Honeywell Durafet ISFET die. When combined with a AgCl pseudoreference sensor that is immersed directly in seawater, the system is capable of operating for years at a time on platforms that cycle from depths of several km to the surface. The paper also describes the calibration scheme developed to allow calibrated pH measurements to be derived from the activity of HCl reported by the sensor system over the range of ocean pressure and temperature. Deployments on vertical profiling platforms enable self-calibration in deep waters where pH values are stable. Measurements with the sensor indicate that it is capable of reporting pH with an accuracy of 0.01 or better on the total proton scale and a precision over multiyear periods of 0.005. This system enables a global ocean observing system for ocean pH.

DOI10.1021/acs.analchem.5b04653
Short TitleAnal. Chem.
Student Publication: 
No
sharknado