Greenhouse gas measurements from a UK network of tall towers: technical description and first results

TitleGreenhouse gas measurements from a UK network of tall towers: technical description and first results
Publication TypeJournal Article
Year of Publication2018
AuthorsStanley K.M, Grant A., O'Doherty S, Young D, Manning A.J, Stavert A.R, Spain T.G, Salameh PK, Harth CM, Simmonds PG, Sturges W.T, Oram D.E, Derwent R.G
JournalAtmospheric Measurement Techniques
Volume11
Pagination1437-1458
Date Published2018/03
Type of ArticleArticle
ISBN Number1867-1381
Accession NumberWOS:000427437200001
Keywordsatmospheric co2; carbon-dioxide; ch4 mole fractions; emissions; high-frequency; in-situ measurements; mace head; Meteorology & Atmospheric Sciences; methane; molecular-hydrogen; nitrous-oxide
Abstract

A network of three tall tower measurement stations was set up in 2012 across the United Kingdom to expand measurements made at the long-term background northern hemispheric site, Mace Head, Ireland. Reliable and precise in situ greenhouse gas (GHG) analysis systems were developed and deployed at three sites in the UK with automated instrumentation measuring a suite of GHGs. The UK Deriving Emissions linked to Climate Change (UK DECC) network uses tall (165-230 m) open-lattice telecommunications towers, which provide a convenient platform for boundary layer trace gas sampling. In this paper we describe the automated measurement system and first results from the UK DECC network for CO2, CH4, N2O, SF6, CO and H-2. CO2 and CH4 are measured at all of the UK DECC sites by cavity ring-down spectroscopy (CRDS) with multiple inlet heights at two of the three tall tower sites to assess for boundary layer stratification. The short-term precisions (1 sigma on 1 min means) of CRDS measurements at background mole fractions for January 2012 to September 2015 is < 0.05 mu mol mol(-1) for CO2 and < 0.3 nmol mol(-1) for CH4. Repeatability of standard injections (1 sigma) is < 0.03 mu mol mol(-1) for CO2 and < 0.3 nmol mol(-1) for CH4 for the same time period. N2O and SF6 are measured at three of the sites, and CO and H-2 measurements are made at two of the sites, from a single inlet height using gas chromatography (GC) with an electron capture detector (ECD), flame ionisation detector (FID) or reduction gas analyser (RGA). Repeatability of individual injections (1 sigma) on GC and RGA instruments between January 2012 and September 2015 for CH4, N2O, SF6, CO and H-2 measurements were <2.8 nmol mol(-1), <0.4 nmol mol(-1), < 0.07 nmol mol(-1), <2 nmol mol(-1) and <3 nmol mol(-1), respectively. Instrumentation in the network is fully automated and includes sensors for measuring a variety of instrumental parameters such as flow, pressures, and sampling temperatures. Automated alerts are generated and emailed to site operators when instrumental parameters are not within defined set ranges. Automated instrument shutdowns occur for critical errors such as carrier gas flow rate deviations. Results from the network give good spatial and temporal coverage of atmospheric mixing ratios within the UK since early 2012. Results also show that all measured GHGs are increasing in mole fraction over the selected reporting period and, except for SF6, exhibit a seasonal trend. CO2 and CH4 also show strong diurnal cycles, with night-time maxima and daytime minima in mole fractions.

DOI10.5194/amt-11-1437-2018
Short TitleAtmos. Meas. Tech.
Student Publication: 
No