Growth in stratospheric chlorine from short-lived chemicals not controlled by the Montreal Protocol

TitleGrowth in stratospheric chlorine from short-lived chemicals not controlled by the Montreal Protocol
Publication TypeJournal Article
Year of Publication2015
AuthorsHossaini R., Chipperfield M.P, Saiz-Lopez A., Harrison J.J, von Glasow R., Sommariva R., Atlas E., Navarro M., Montzka SA, Feng W., Dhomse S., Harth C, Mühle J, Lunder C., O'Doherty S, Young D, Reimann S., Vollmer M.K, Krummel PB, Bernath P.F
JournalGeophysical Research Letters
Volume42
Pagination4573-4580
Date Published2015/06
ISBN Number1944-8007
Keywords0365 Troposphere: composition and chemistry; 0368 Troposphere: constituent transport and chemistry; dichloromethane; montreal protocol; ozone; phosgene; stratosphere; VSLS
Abstract

We have developed a chemical mechanism describing the tropospheric degradation of chlorine containing very short-lived substances (VSLS). The scheme was included in a global atmospheric model and used to quantify the stratospheric injection of chlorine from anthropogenic VSLS ( ClyVSLS) between 2005 and 2013. By constraining the model with surface measurements of chloroform (CHCl3), dichloromethane (CH2Cl2), tetrachloroethene (C2Cl4), trichloroethene (C2HCl3), and 1,2-dichloroethane (CH2ClCH2Cl), we infer a 2013 ClyVSLS mixing ratio of 123 parts per trillion (ppt). Stratospheric injection of source gases dominates this supply, accounting for ∼83% of the total. The remainder comes from VSLS-derived organic products, phosgene (COCl2, 7%) and formyl chloride (CHClO, 2%), and also hydrogen chloride (HCl, 8%). Stratospheric ClyVSLS increased by ∼52% between 2005 and 2013, with a mean growth rate of 3.7 ppt Cl/yr. This increase is due to recent and ongoing growth in anthropogenic CH2Cl2—the most abundant chlorinated VSLS not controlled by the Montreal Protocol.

DOI10.1002/2015GL063783
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